Synthesis of 1,4-Benzoxazine Adducts of Fullerene C60 in the Presence of Lead(IV) Acetate
摘要
Abstract
A method has been developed for the synthesis of new fused 1,4-benzoxazine monoadducts of fullerene C60 by the reaction with 2-aminophenols (2-aminophenol, 2-amino-4-methylphenol, 3-amino-[1,1′-biphenyl]-4-ol) in the presence of LiOH and Pb(OAc)4. A probable reaction mechanism has been proposed.