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Abstract <p>The acylation behavior of several nucleophiles with adamantan-2-ylidenemalonic acid dichloride was investigated. The reactivity of adamantan-2-ylidenemalonic acid and its derivatives toward reducing systems was examined. A skeletal rearrangement of adamantan-2-ylidenemalonic acid in liquid bromine was revealed, affording bromolactones possessing a protoadamantane framework.</p>

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Chemical Transformations of Adamantan-2-ylidenemalonic Acid and Its Derivatives

  • 期刊论文

  • 发表日期：

    2026年7月30日

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  • Andrei V. Merzlyakov,
  • Anastasiya N. Dobrokvashina,
  • Yuri N. Klimochkin

摘要

Abstract

The acylation behavior of several nucleophiles with adamantan-2-ylidenemalonic acid dichloride was investigated. The reactivity of adamantan-2-ylidenemalonic acid and its derivatives toward reducing systems was examined. A skeletal rearrangement of adamantan-2-ylidenemalonic acid in liquid bromine was revealed, affording bromolactones possessing a protoadamantane framework.