Scholarlink

Abstract <p>Herein, we report a metal-free, photoelectrochemical (PEC) strategy for the direct C<i>–</i>H amination of guaiacol. Using a rationally designed PEC system, we achieved efficient amination with a range of nitrogen nucleophiles, including phenothiazines (PTZs) and phenoxazine (PNX), affording the corresponding products in yields of up to 90%. This operationally simple protocol demonstrates the unique potential of PEC to enable challenging transformations under mild conditions, providing a sustainable route to valuable <i>N</i>-arylamines.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Photoelectrochemical C–H Amination of Guaiacol

  • 期刊论文

  • 发表日期：

    2025年12月1日

查看全文
  • Maria A. Khvorova,
  • Sofia O. Strekalova,
  • Alexander I. Kononov,
  • Radel R. Mingazov,
  • Vladimir I. Morozov,
  • Guzel R. Strekalova,
  • Yulia H. Budnikova

摘要

Abstract

Herein, we report a metal-free, photoelectrochemical (PEC) strategy for the direct C–H amination of guaiacol. Using a rationally designed PEC system, we achieved efficient amination with a range of nitrogen nucleophiles, including phenothiazines (PTZs) and phenoxazine (PNX), affording the corresponding products in yields of up to 90%. This operationally simple protocol demonstrates the unique potential of PEC to enable challenging transformations under mild conditions, providing a sustainable route to valuable N-arylamines.