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Abstract <p>A stepwise synthesis of 2-(phenoxymethyl)oxirane derivatives was carried out by reacting this epoxide with various amines, phenols, and alcohols. β-Amino alcohols, 1,4-dioxane derivatives, and heterocyclic compounds containing isoxazole, pyrazole, and oxazolidine fragments were obtained. The structures of the compounds were confirmed by IR and NMR spectroscopy (<sup>1</sup>H, <sup>13</sup>C) and elemental analysis. The regioselectivity and chemoselectivity of epoxide ring opening and the cyclization features of the amine derivatives were studied.</p>

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Synthesis and Chemical Modification of Phenylglycidyl Ether

  • 期刊论文

  • 发表日期：

    2025年11月1日

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  • M. I. Shatirova,
  • M. E. Gasanova

摘要

Abstract

A stepwise synthesis of 2-(phenoxymethyl)oxirane derivatives was carried out by reacting this epoxide with various amines, phenols, and alcohols. β-Amino alcohols, 1,4-dioxane derivatives, and heterocyclic compounds containing isoxazole, pyrazole, and oxazolidine fragments were obtained. The structures of the compounds were confirmed by IR and NMR spectroscopy (1H, 13C) and elemental analysis. The regioselectivity and chemoselectivity of epoxide ring opening and the cyclization features of the amine derivatives were studied.