Scholarlink

Abstract <p>An efficient one-step method for preparation of mesoionic derivatives of sterically hindered benzodioxolenes containing an annulated 2-aryl-1,3-dithiole fragment was developed. The anionic and cationic parts in these species are predominantly localized on the dioxolene site and in the 1,3-dithiole heterocycle, respectively. The nature of the aryl substituent in the 2-position of the 1,3-dithiole cycle determines the spatial structure of the molecule and the features of intermolecular interactions during the formation of packing in the crystalline phase.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Design of a New Class of Mesoionic Compounds Based on Benzodioxolene Derivatives with Annulated 2-Aryl-1,3-dithiolium Moiety

  • 期刊论文

  • 发表日期：

    2025年7月1日

查看全文
  • S. V. Norkov,
  • S. G. Makarov,
  • E. V. Baranov,
  • G. K. Fukin,
  • G. V. Romanenko,
  • V. A. Kuropatov

摘要

Abstract

An efficient one-step method for preparation of mesoionic derivatives of sterically hindered benzodioxolenes containing an annulated 2-aryl-1,3-dithiole fragment was developed. The anionic and cationic parts in these species are predominantly localized on the dioxolene site and in the 1,3-dithiole heterocycle, respectively. The nature of the aryl substituent in the 2-position of the 1,3-dithiole cycle determines the spatial structure of the molecule and the features of intermolecular interactions during the formation of packing in the crystalline phase.