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Abstract <p>A simple procedure for obtaining previously unknown diphthalonitriles based on 4-nitrophthalonitrile and 3,3′,5,5′-tetrasubstituted biphenyl-4,4′-diol derivatives in a binary solvent system DMF–water was developed. The possibilities and limitations of using 3,3′,5,5′-tetrasubstituted biphenyl-2,2′-diol derivatives as reagents for the synthesis of diphthalonitriles and corresponding dianhydrides were demonstrated. The effect of the substrate nature on the yield of target diphthalonitriles was considered using 2,2′,3,3′,5,5′-hexamethylbiphenyl-4,4′-diol as an example.</p>

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Synthesis of Diphthalonitriles Based on 3,3′,5,5′-Tetrasubstituted Derivatives of 2,2′- and 4,4′-Biphenyldiols

  • 期刊论文

  • 发表日期：

    2025年5月21日

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  • V. L. Baklagin,
  • V. V. Bukhalin,
  • E. A. Zyuzin,
  • I. G. Abramov

摘要

Abstract

A simple procedure for obtaining previously unknown diphthalonitriles based on 4-nitrophthalonitrile and 3,3′,5,5′-tetrasubstituted biphenyl-4,4′-diol derivatives in a binary solvent system DMF–water was developed. The possibilities and limitations of using 3,3′,5,5′-tetrasubstituted biphenyl-2,2′-diol derivatives as reagents for the synthesis of diphthalonitriles and corresponding dianhydrides were demonstrated. The effect of the substrate nature on the yield of target diphthalonitriles was considered using 2,2′,3,3′,5,5′-hexamethylbiphenyl-4,4′-diol as an example.