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Synthesis, Structure, and Properties of Rhodium(II) Acetate Complexes with 2H-Azirines

  • 期刊论文

  • 发表日期：

    2024年1月1日

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  • A. V. Grishin,
  • I. P. Filippov,
  • N. V. Rostovskii

摘要

Abstract

Complexes of rhodium(II) acetate with 2H-azirines were obtained for the first time. The 1 : 2 complexes were characterized using 1H and 13C NMR, IR, and UV spectroscopy and high-resolution mass spectrometry. The structure of Rh2(OAc)4 complex with two 3-(4-methoxyphenyl)-2H-azirine molecules was studied by X-ray diffraction analysis. In crystal, the molecule of this complex belongs to the Ci point group.