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Mechanochemical Synthesis of Fluorine-Conducting Solid Electrolytes Based on Tysonite and Fluorite Structures

  • N. A. Melnikova,
  • Qianlong Ji,
  • Baijun Fei,
  • O. V. Glumov,
  • I. V. Murin

摘要

Abstract

The possibilities of the mechanochemical synthesis of new fluorine-conducting solid electrolytes based on tysonite and fluorite structures were considered. For the first time, solid solutions in the CeF3–SnF2 system with SnF2 content of 5–30 mol % were synthesized. The possibility of stabilizing the structure of fluorite in solid solutions based on lead(II) fluorine under the conditions of mechanochemical synthesis has been demonstrated.