Synthesis and Optical Properties of a Polyyne Dendrimer

期刊论文
发表日期：

2024年9月1日

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P. Xu,
Y.-L. Zuo,
N.-W. Sun,
L. Zhai,
K. Yin,
H.-F. Chen,
X. Qin,
X.-Y. Lin,
J.-Y. Zou,
J.-L. Zhang

摘要

Abstract

A polyyne dendrimer (PD) was synthesized in four-steps and characterized by ¹H NMR, ¹³C NMR, MS, FT-IR, etc. Subsequently, ultraviolet visible (UV-Vis) absorption spectra and fluorescence spectra were further investigated in a series of solvents, in which obvious aggregation-induced emission (AIE) were observed. In addition, the electrochemiluminescence (ECL)properties in solid state were also investigated. Interestingly, the π-extended PD with slight distorted configuration possessed intense and stable cathodic ECL emission, which indicatedthat it has potential application in the future construction of high-performance ECL emitters.