Synthesis of New Unsymmetrical Cage Phosphonates Based on 4-Aryl-2-hydroxy-5,7,8-trimethylbenzo[e][1,2]oxaphosphinine-2-oxides
摘要
Abstract
A new phosphaneoflavonoid was obtained by the reaction oxaphosphinine with β-resorcylic acid. A method was proposed for the synthesis of new unsymmetrical cage phosphonates based on 4-aryl-2-hydroxy-5,7,8-trimethylbenzo[e][1,2]oxaphosphinine-2-oxides as a result of intramolecular heterocyclization. Composition and structure of all the obtained compounds were confirmed by 1H, 13С and 31P NMR, IR spectroscopy and mass spectrometry data.