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Synthesis of New Unsymmetrical Cage Phosphonates Based on 4-Aryl-2-hydroxy-5,7,8-trimethylbenzo[e][1,2]oxaphosphinine-2-oxides

  • A. V. Zalaltdinova,
  • Yu. M. Sadykova,
  • A. S. Gazizov,
  • A. K. Smailov,
  • А. R. Burilov

摘要

Abstract

A new phosphaneoflavonoid was obtained by the reaction oxaphosphinine with β-resorcylic acid. A method was proposed for the synthesis of new unsymmetrical cage phosphonates based on 4-aryl-2-hydroxy-5,7,8-trimethylbenzo[e][1,2]oxaphosphinine-2-oxides as a result of intramolecular heterocyclization. Composition and structure of all the obtained compounds were confirmed by 1H, 13С and 31P NMR, IR spectroscopy and mass spectrometry data.