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New Heterocyclization Reactions with Malononitrile Dimer

  • A. O. Kurskova,
  • B. S. Krivokolysko,
  • V. V. Dotsenko,
  • N. A. Aksenov,
  • I. V. Aksenova,
  • S. G. Krivokolysko

摘要

Abstract

New approaches based on multicomponent condensation reactions were proposed to the synthesis of new heterocyclic derivatives of malononitrile dimer of the series of 7-oxa-1,3,6-triazabenzo[no]tetraphene, 1,2,3,4-tetrahydropyrazolo[1,5-a][1,3,5]triazine, 1,3,5,5-tetracyanocyclohex-3-ene, 3,9-diazaspiro[5.5]undeca-1,4-diene and 1Н,5Н-spiro[3,7-diazabicyclo[3.3.1]non-2-ene-9,4'-piperidine]. Structure of the products was studied using mass spectrometry, IR and NMR spectroscopy, as well as X-ray diffraction analysis.