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Synthesis of 1,2,4-Triazolo[1,5-d][1,2,4]triazine-2-amines by Thermolysis of 1H-Tetrazol-5-amine with 1,2,4-Triazine-5-carbonitriles

  • Ya. K. Shtaitz,
  • E. D. Ladin,
  • D. S. Kopchuk,
  • I. A. Khalymbadzha,
  • V. S. Gaviko,
  • G. V. Zyryanov,
  • D. V. Antonenko,
  • V. A. Ostrovskii,
  • V. L. Rusinov

摘要

Abstract

A novel method for the synthesis of 1,2,4-triazolo[1,5-d][1,2,4]triazine-2-amines by solvent-free thermolysis of the 1H-tetrazole-5-amine in presence of the 1,2,4-triazine-5-carbonitriles has been proposed. A mechanism of found interaction has been suggested.