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Complexation of Europium(III) and Terbium(III) Ions with Terephthalic Acid in Aqueous Solutions

  • Ya. E. Saitov,
  • P. B. Guseva,
  • Yu. N. Toikka,
  • N. A. Bogachev,
  • M. Yu. Skripkin,
  • A. S. Mereshchenko

摘要

Abstract

The stability constants of the complexes of europium(III) and terbium(III) ions with terephthalic acid anions were determined by potentiometric titration over a wide pH range. The luminescent properties of these complexes were studied. It was shown that the complexes are most stable in slightly acidic solutions. Analysis of the photoluminescence emission spectra confirmed the adequacy of the proposed model of complexation.