2-Allyl- and 2-Benzylmaleopimarimide Acyl Isothiocyanates: Synthesis of Triazoles
摘要
Abstract
The reaction of acyl isothiocyanates of 2-allyl- and 2-benzylmaleopimarimides with ethyl-, benzylhydrazine, or ethyl ester of hydrazinoacetic acid leads to the formation of maleopimarimides containing the fragment of 5-thioxo-2,5-dihydro-1H-1,2,4-triazole. The structures of the synthesized compounds were determined by 1H, 13C, 1H–13C HSQC, 1H–13C HMBC, COSY, NOESY, and 1H-15N HMBC NMR spectroscopy methods.