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Abstract <p>The triphenylgermanium cumylperoxide, Ph<sub>3</sub>GeOOCm was synthesized and characterized using single-crystal X-ray diffraction (scXRD), powder X-ray diffraction (PXRD), FTIR and Raman spectroscopy, thermal analysis, and elemental analysis. According to the single-crystal X-ray diffraction analysis triphenylgermanium cumylperoxide crystallizes in the triclinic <InlineEquation ID="IEq1"> <EquationSource Format="TEX">\(P\bar {1}\)</EquationSource> <!--CoChem2560159Egorov-m1--> </InlineEquation> space group with <i>Z</i> = 2. The stability of Ph<sub>3</sub>GeOOCm complex to hydrolysis was characterized by <sup>1</sup>H NMR spectroscopy in toluene, DMSO, and DMF.</p>

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Synthesis and Crystal Structure of Triphenylgermanium Cumylperoxide

  • 期刊论文

  • 发表日期：

    2025年12月1日

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  • P. A. Egorov,
  • T. A. Tripol’skaya,
  • E. A. Mel’nik,
  • A. A. Mikhaylov,
  • P. V. Prikhodchenko

摘要

Abstract

The triphenylgermanium cumylperoxide, Ph3GeOOCm was synthesized and characterized using single-crystal X-ray diffraction (scXRD), powder X-ray diffraction (PXRD), FTIR and Raman spectroscopy, thermal analysis, and elemental analysis. According to the single-crystal X-ray diffraction analysis triphenylgermanium cumylperoxide crystallizes in the triclinic \(P\bar {1}\) space group with Z = 2. The stability of Ph3GeOOCm complex to hydrolysis was characterized by 1H NMR spectroscopy in toluene, DMSO, and DMF.