Scholarlink

Abstract <p>Five new bromide complexes of antimony(III) and bismuth(III) with dicationic species (3‑ClPyC<sub>6</sub>)[SbBr<sub>6</sub>]<sub>2</sub> (<b>I</b>), (3-ClPyC<sub>6</sub>)<sub>2</sub>[Sb<sub>4</sub>Br<sub>16</sub>] (<b>II</b>), (3-ClPyC<sub>6</sub>)<sub>3</sub>[Bi<sub>2</sub>Br<sub>9</sub>]<sub>2</sub> (<b>III</b>), (3-BrPyC<sub>6</sub>)<sub>3</sub>[Sb<sub>2</sub>Br<sub>9</sub>]<sub>2</sub> (<b>IV</b>), and (3-BrPyC<sub>6</sub>)<sub>3</sub>[Bi<sub>2</sub>Br<sub>9</sub>]<sub>2</sub> (<b>V</b>) based on substituted 3-halopyridines {(3-XPy)<sub>2</sub>(CH<sub>2</sub>)<sub>6</sub>}<sup>2+</sup> (X = Cl, Br) were obtained. The structures of the compounds were determined by X-ray diffraction analysis (CCDC nos. 2457726–2457730). The features of halogen···halogen interactions between the cations and anions were analyzed.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Bi- and Tetranuclear Bromide Complexes of Antimony(III) and Bismuth(III) with 1,1'-(Hexane-1,6-diyl)bis(3-halopyridinium) Cations

  • 期刊论文

  • 发表日期：

    2025年9月1日

查看全文
  • I. A. Shentseva,
  • A. N. Usol’tsev,
  • N. A. Korobeinikov,
  • M. N. Sokolov,
  • S. A. Adonin

摘要

Abstract

Five new bromide complexes of antimony(III) and bismuth(III) with dicationic species (3‑ClPyC6)[SbBr6]2 (I), (3-ClPyC6)2[Sb4Br16] (II), (3-ClPyC6)3[Bi2Br9]2 (III), (3-BrPyC6)3[Sb2Br9]2 (IV), and (3-BrPyC6)3[Bi2Br9]2 (V) based on substituted 3-halopyridines {(3-XPy)2(CH2)6}2+ (X = Cl, Br) were obtained. The structures of the compounds were determined by X-ray diffraction analysis (CCDC nos. 2457726–2457730). The features of halogen···halogen interactions between the cations and anions were analyzed.