Abstract <p>A new trinuclear manganese(II) carboxylate complex [Mn<sub>3</sub>L<sub>2</sub>(OAc)<sub>6</sub>] (<b>I</b>), where L is diisopropyl(pyridin-2-ylmethyl)phosphine oxide, was synthesized. The composition of complex <b>I</b> was confirmed by mass spectrometry, IR spectroscopy, and elemental analysis. The crystal structure of the complex was determined by X-ray diffraction (CCDC no. 2447670). The luminescence and cytotoxicity of <b>I</b> were studied in relation to M-HeLa and HuTu80 cancer cell lines and Chang Liver normal cell line It was found that compound <b>I</b> exhibited high cytotoxicity against the HuTu80 cancer cells.</p>

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Trinuclear Manganese(II) Complex Based on Diisopropyl(pyridin-2-ylmethyl)phosphine Oxide

  • K. R. Enikeeva,
  • D. R. Islamov,
  • S. K. Amerhanova,
  • A. D. Voloshina,
  • I. E. Kolesnikov,
  • E. I. Musina,
  • A. A. Karasik

摘要

Abstract

A new trinuclear manganese(II) carboxylate complex [Mn3L2(OAc)6] (I), where L is diisopropyl(pyridin-2-ylmethyl)phosphine oxide, was synthesized. The composition of complex I was confirmed by mass spectrometry, IR spectroscopy, and elemental analysis. The crystal structure of the complex was determined by X-ray diffraction (CCDC no. 2447670). The luminescence and cytotoxicity of I were studied in relation to M-HeLa and HuTu80 cancer cell lines and Chang Liver normal cell line It was found that compound I exhibited high cytotoxicity against the HuTu80 cancer cells.