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Abstract <p>Two new Co(II) and Zn(II) metal-organic coordination polymers with 2,2'-diiodobiphenyl-4,4'-dicarboxylate linkers, [Co<sub>2</sub>(bpdc-I<sub>2</sub>)<sub>2</sub>(bpp)(DMF)]·0.75DMF (<b>I</b>) and [Zn<sub>4</sub>O(bpdc-I<sub>2</sub>)<sub>3</sub>]·7DMF (<b>II</b>), were prepared (bpdc-I<sub>2</sub> is 2,2'-diiodobiphenyl-4,4'-dicarboxylate, bpp is 1,3-bis(4-pyridyl)propane). The structure of the products was established by X-ray diffraction. Compound <b>II</b> has a three-dimensional structure with the calculated accessible volume of 53.2%.</p>

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Crystal Structures of Two New Metal-Organic Coordination Polymers Based on Co(II) or Zn(II) and 2,2'-Diiodobiphenyl-4,4'-dicarboxylate

  • 期刊论文

  • 发表日期：

    2025年6月1日

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  • A. S. Zaguzin,
  • A. V. Zaitsev,
  • M. A. Bondarenko,
  • N. A. Korobeinikov,
  • I. V. Korol’kov,
  • I. A. Lystsov,
  • I. F. Sakhapov,
  • R. V. Red’kin,
  • E. A. Pilyukova,
  • P. E. Plyusnin,
  • M. N. Sokolov,
  • V. P. Fedin,
  • S. A. Adonin

摘要

Abstract

Two new Co(II) and Zn(II) metal-organic coordination polymers with 2,2'-diiodobiphenyl-4,4'-dicarboxylate linkers, [Co2(bpdc-I2)2(bpp)(DMF)]·0.75DMF (I) and [Zn4O(bpdc-I2)3]·7DMF (II), were prepared (bpdc-I2 is 2,2'-diiodobiphenyl-4,4'-dicarboxylate, bpp is 1,3-bis(4-pyridyl)propane). The structure of the products was established by X-ray diffraction. Compound II has a three-dimensional structure with the calculated accessible volume of 53.2%.