Scholarlink

Abstract <p>In recent years, the trend towards developing more efficient and green approaches to the synthesis of chemical compounds has engulfed new areas of chemistry, including organometallic synthesis. In this work, the peculiarities of direct cyclopalladation of <i>m</i>-phenylenediamine-based bis(thioamide) ligands are studied both in solution and in the absence of a solvent in order to estimate the possibility of obtaining target Pd(II) pincer complexes using a more ecologically friendly methodology.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Solid-Phase Cyclopalladation of Bis(thioamide) Pincer Ligands Based on m-Phenylenediamine

  • 期刊论文

  • 发表日期：

    2025年3月1日

查看全文
  • D. V. Aleksanyan,
  • Yu. V. Nelyubina,
  • Z. S. Klemenkova,
  • V. A. Kozlov

摘要

Abstract

In recent years, the trend towards developing more efficient and green approaches to the synthesis of chemical compounds has engulfed new areas of chemistry, including organometallic synthesis. In this work, the peculiarities of direct cyclopalladation of m-phenylenediamine-based bis(thioamide) ligands are studied both in solution and in the absence of a solvent in order to estimate the possibility of obtaining target Pd(II) pincer complexes using a more ecologically friendly methodology.