Cadmium(II) Complexes with Redox-Active Indophenol Ligands: Synthesis and Structures

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发表日期：

2024年3月1日

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E. P. Ivakhnenko,
Yu. G. Vitkovskaya,
N. I. Merezhko,
P. A. Knyazev,
G. S. Borodkin,
K. A. Lysenko,
V. I. Minkin

摘要

Abstract

The Сd(II) complexes with redox amphoteric 2,6-di-(tert-butyl)-4-((2-hydroxyphenyl)imino)cyclohexa-2,5-dienone ligands L¹ and L² (adducts I, II, and III) are synthesized. The structures of coordinated complexes I, II, and III are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 1838319 (II) and 1838310 (III)) and confirmed by the ¹Н, ¹³С, and ¹¹³Cd NMR spectroscopy (for complexes I and III) and IR spectroscopy data.