Investigation of Carrier Recombination in Polycrystalline Silicon Thin-Film Solar Cells
摘要
Developing efficient polycrystalline silicon (pc-Si) thin-film solar cells offers a promising route to reducing photovoltaic costs, but their performance is strongly constrained by carrier recombination. In this work, a two-dimensional device simulation is developed to analyse recombination mechanisms in pc-Si thin-film solar cells, incorporating Gaussian and tail-distributed donor- and acceptor-like traps for bulk recombination and delta-distributed traps for interface recombination. Both Shockley–Read–Hall (SRH) and auger recombination, along with interface recombination, are examined in detail. Results show that increasing defect density enhances both SRH and auger recombination, with SRH dominating below emitter doping densities of 1016 cm–3 and auger recombination prevailing above this level; however, SRH remains dominant across absorber defect densities from 1014 to 1019 cm–3. Interface trap densities between 1011 and 1013 cm–2 are found to significantly degrade performance, underscoring the need for bulk and interface trap passivation. Device performance metrics; short-circuit current density (JSC), open-circuit voltage (VOC), fill factor (FF), and efficiency are further evaluated against variations in absorber bandgap, absorber thickness, and emitter doping concentration. For an optimized absorber thickness of 3 μm, absorber bandgap of 1.3 eV, emitter doping of 1018 cm–3, and interface trap density of 1012 cm–2, the model predicts a maximum efficiency of ~9.6%. The developed model is in good agreement with reported experimental results.