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Structure, Spectral Characteristics, and Phase Transitions in the Rb3CoCl4NO3 Crystal

  • A. V. Gudymenko,
  • V. A. Komornikov,
  • N. I. Sorokina,
  • T. A. Sorokin,
  • I. S. Timakov,
  • D. S. Matveeva,
  • A. E. Voloshin

摘要

Abstract

Rb3CoCl4NO3 samples applicable for studying spectral characteristics have been obtained for the first time and investigated in the wavelength range λ = 200–800 nm. Transparency windows are found at the UV–visible and visible–IR boundaries. Differential-scanning calorimetry/thermogravimetry analysis revealed that the Rb3CoCl4NO3 crystal is thermally stable, melts without decomposition, and undergoes two reversible phase transitions. The structure of Rb3CoCl4NO3 single crystals was studied by X-ray diffraction in the temperature range of 293–625 K.