Abstract <p>We have synthesized a new series of heteroleptic halogen-substituted complexes with the general formula [XL<sub>2</sub>Bipy]Cl, where L = 1-(4-fluorophenyl)-3-(4-bromophenyl)-propane-1,3-dione; Bipy = 2,2'-bipyridine; and X = Fe<sup>3+</sup>, Ga<sup>3+</sup>, Eu<sup>3+</sup>. Their structure and phase behavior have been studied and their magnetic properties have been investigated in a wide temperature range and analyzed theoretically.</p>

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A New Functional Series of Mixed-Ligand Fe(III), Ga(III), and Eu(III) β-Diketonate Complexes: Evolution of Magnetic States

  • D. V. Starichenko,
  • M. S. Gruzdev,
  • U. V. Chervonova,
  • V. E. Vorobeva,
  • A. S. Volegov,
  • I. V. Yatsyk

摘要

Abstract

We have synthesized a new series of heteroleptic halogen-substituted complexes with the general formula [XL2Bipy]Cl, where L = 1-(4-fluorophenyl)-3-(4-bromophenyl)-propane-1,3-dione; Bipy = 2,2'-bipyridine; and X = Fe3+, Ga3+, Eu3+. Their structure and phase behavior have been studied and their magnetic properties have been investigated in a wide temperature range and analyzed theoretically.