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Abstract <p>The question of the quantitative composition and structure of the formed hydrogen complexes of the 1,2-naphthoquinone molecule with water molecules in its hydration shell is considered. The problem was solved by comparing the calculated shifts of electronic transitions during the formation of hydrogen complexes with <i>n</i> = 5–13 water molecules with the experimental shifts of the absorption bands of 1,2-naphthoquinone in a water solution compared to a solution in <i>n</i>-hexane.</p>

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Structure of Hydrogen Complexes in Hydrates of the 1,2-Naphthoquinone Molecule

  • 期刊论文

  • 发表日期：

    2025年3月1日

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  • S. N. Tseplina,
  • E. E. Tseplin

摘要

Abstract

The question of the quantitative composition and structure of the formed hydrogen complexes of the 1,2-naphthoquinone molecule with water molecules in its hydration shell is considered. The problem was solved by comparing the calculated shifts of electronic transitions during the formation of hydrogen complexes with n = 5–13 water molecules with the experimental shifts of the absorption bands of 1,2-naphthoquinone in a water solution compared to a solution in n-hexane.