Effect of a Substitute in a Ligand and a Counterion on the Properties of a Heptanuclear Mixed-Valence Iron Complex

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发表日期：

2024年7月1日

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E. E. Batueva,
A. R. Sharipova,
E. N. Frolova,
L. I. Savostina,
L. V. Bazan,
M. A. Cherosov,
R. G. Batulin,
O. A. Turanova,
A. N. Turanov

摘要

Abstract

New heptanuclear mixed-valence iron complexes with pentadentate ligands are synthesized, and their magnetic properties are analyzed. Magnetometry and EPR show that thiocyanate anions promote spin-crossover properties. Introducing long alkoxy chains into a molecule gives it thermotropic liquid crystalline properties and enhances its cooperative magnetic properties.