Abstract <p>The paper presents the results of molecular dynamics simulating microscopic collective excitations in low-density amorphous ice, with the simulation being based on the monatomic ML-mW model of the intermolecular interaction potential. The calculated spectra of longitudinal <InlineEquation ID="IEq1"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="10595_2025_8619_Article_IEq1.gif" Format="GIF" Height="19" Rendition="HTML" Resolution="72" Type="Linedraw" Width="62" /> </InlineMediaObject> <EquationSource Format="TEX">\({{C}_{{\text{L}}}}(k,\omega )\)</EquationSource> <!--CollJour2460141Khusnutdinoff-m1--> </InlineEquation> and transverse <InlineEquation ID="IEq2"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="10595_2025_8619_Article_IEq2.gif" Format="GIF" Height="19" Rendition="HTML" Resolution="72" Type="Linedraw" Width="63" /> </InlineMediaObject> <EquationSource Format="TEX">\({{C}_{{\text{T}}}}(k,\omega )\)</EquationSource> <!--CollJour2460141Khusnutdinoff-m2--> </InlineEquation> current spectra have revealed the propagation of collective excitations of the longitudinal and transverse polarizations in amorphous ice within a wide range of wavenumbers. The region of mixing the longitudinal and transverse collective modes in low-density amorphous ice has been found. It has been shown that, in terms of the dispersion law of transverse acoustic-like modes, the temperature dependence of gap width <i>k</i><sub>gap</sub> is described by a linear dependence.</p>

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Collective Excitations in Amorphous Ice

  • R. M. Khusnutdinoff

摘要

Abstract

The paper presents the results of molecular dynamics simulating microscopic collective excitations in low-density amorphous ice, with the simulation being based on the monatomic ML-mW model of the intermolecular interaction potential. The calculated spectra of longitudinal \({{C}_{{\text{L}}}}(k,\omega )\) and transverse \({{C}_{{\text{T}}}}(k,\omega )\) current spectra have revealed the propagation of collective excitations of the longitudinal and transverse polarizations in amorphous ice within a wide range of wavenumbers. The region of mixing the longitudinal and transverse collective modes in low-density amorphous ice has been found. It has been shown that, in terms of the dispersion law of transverse acoustic-like modes, the temperature dependence of gap width kgap is described by a linear dependence.