Layered Niobium-Cermet Composite Material
摘要
Layered composite materials based on niobium and cermet are produced via the self-propagating high-temperature synthesis of preliminarily structured samples using metal foils (Ti, Nb, Ta, Ni) and reaction tapes (Ti + 1.7B) and (5Ti + 3Si). The reaction tapes for synthesis are produced by rolling powder mixtures. The microstructure, and elemental and phase compositions of the synthesized multilayer composite materials are studied by scanning electron microscopy and X-ray phase analysis. Particular attention is paid to the formation of intermediate layers and surface modification occurring during combustion. The strength characteristics of the synthesized materials are determined according to the three-point loading scheme at temperatures of 1100°C. Analysis of the obtained materials shows that joining in the combustion mode of metal foils and reaction tapes is provided due to reaction diffusion, mutual impregnation, and chemical reactions occurring in the reaction tapes and on the surface of the metal foils. The formation of thin intermediate layers in the form of cermet and eutectic solutions provides the synthesized multilayer materials with good strength properties up to 87 MPa at 1100°C. These results are of interest for the development of structural materials operating under extreme conditions.