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Synthesis and Electrocatalytic Activity of Graphene–Phosphorene Structures Decorated with Cobalt Atoms

  • R. A. Manzhos,
  • N. S. Komarova,
  • A. S. Kotkin,
  • V. K. Kochergin,
  • T. R. Prikhodchenko,
  • A. G. Krivenko

摘要

Abstract

Nitrogen-doped few-layered graphene structures are synthesized by plasma-assisted electrochemical exfoliation of graphite and used in the preparation of composites with phosphorene structures obtained by supersonic exfoliation of a porous black-phosphorus electrode covered with preliminarily deposited cobalt. The catalytic activity in the hydrogen evolution reaction is studied for the few-layered graphene and phosphorene structures, as well as their mixtures. The mixed electrocatalysts demonstrate the highest activity in the hydrogen evolution reaction.