Abstract <p>The carbothermic production of a titanium-containing ferroalloy is subjected to thermodynamic modeling. The Ti–Al–Si–Fe–C–O system is studied using the HSC Chemistry software package. At a low quartzite content in a charge, stable carbide phases TiC and SiC are found to form and prevent metallic phase formation. An increase in the quartzite content to 10–15% is shown to suppresses carbide formation and to promote the formation of silicides TiSi, TiSi<sub>2</sub>, and Ti<sub>3</sub>Si<sub>3</sub>.</p>

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Thermodynamic Modeling of the Carbothermic Melting of a Complex Titanium-Containing Ferroalloy

  • N. R. Vorobkalo,
  • A. S. Baisanov,
  • A. K. Makishev,
  • S. S. Sharieva,
  • Zh. A. Ibrakhimova

摘要

Abstract

The carbothermic production of a titanium-containing ferroalloy is subjected to thermodynamic modeling. The Ti–Al–Si–Fe–C–O system is studied using the HSC Chemistry software package. At a low quartzite content in a charge, stable carbide phases TiC and SiC are found to form and prevent metallic phase formation. An increase in the quartzite content to 10–15% is shown to suppresses carbide formation and to promote the formation of silicides TiSi, TiSi2, and Ti3Si3.