Preparation of the Coating on the C/C–SiC Composite from the Mo–HfSi2–SiB4 Composition by the In Situ Reaction Synthesis
摘要
Abstract
The coating based on the MoSi2–MoB–HfB2 system on the substrate of the C/C–SiC composite is prepared by the in situ reaction synthesis using the slurry-roasting deposition of the powder composition at 1620°C under an argon expansion pressure of ~1 Pa. The reaction mechanisms in the Mo–HfSi2–SiB4–C system predetermining the synthesis of secondary phases MoSi2, MoB, HfB2, and HfC are proposed. Thermodynamic calculations of possible chemical reactions are performed. Probable causes for a high porosity of the prepared coating are analyzed.