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Abstract <p>The stability constants of the coordination compounds of silver(I) ions with 18-crown-6 ether in mixed methanol–acetonitrile solvents (MeOH–AN, <i>x</i><sub>AN</sub> = 0–1 mole fraction, 25°C) were determined by potentiometry. The results were discussed in terms of the solvation-thermodynamic approach based on the thermodynamic characteristization of solvation of all the compounds involved in chemical equilibrium.</p>

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Effects of Reagent Solvation on the Stability of the Coordination Compounds of Silver(I) with 18-Crown-6 Ether in Mixed Methanol–Acetonitrile Solvents

  • 期刊论文

  • 发表日期：

    2026年2月1日

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  • I. A. Kuz’mina,
  • M. A. Kovanova

摘要

Abstract

The stability constants of the coordination compounds of silver(I) ions with 18-crown-6 ether in mixed methanol–acetonitrile solvents (MeOH–AN, xAN = 0–1 mole fraction, 25°C) were determined by potentiometry. The results were discussed in terms of the solvation-thermodynamic approach based on the thermodynamic characteristization of solvation of all the compounds involved in chemical equilibrium.