Abstract <p>The electrochemical behavior of tricyclic monoperoxide on a smooth gold electrode in an acetonitrile solution was studied by cyclic voltammetry (CV). It was found that the cathodic process involves the joint transfer of two electrons. In the anodic process, the electrode corrodes, forming gold nanoparticles. A&#xa0;mechanism for the reduction of monoperoxide to triketone was proposed.</p>

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Electrochemical Behavior of Tricyclic Monoperoxide in an Acetonitrile Solution on Smooth Gold

  • M. V. Polyakov,
  • M. D. Vedenyapina,
  • A. M. Skundin,
  • I. A. Yaremenko,
  • P. S. Radulov

摘要

Abstract

The electrochemical behavior of tricyclic monoperoxide on a smooth gold electrode in an acetonitrile solution was studied by cyclic voltammetry (CV). It was found that the cathodic process involves the joint transfer of two electrons. In the anodic process, the electrode corrodes, forming gold nanoparticles. A mechanism for the reduction of monoperoxide to triketone was proposed.