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Abstract <p>Fries’ photo-rearrangement of the thioester of para-methyl benzocarbothiol in a number of solvents is studied by means of CIDNP. It is shown that the reaction proceeds with the formation of radical pairs in the singlet state. Elementary stages of the reaction are determined.</p>

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Investigating the Photoregrouping of Thioester Esters Based on Effects from the Chemical Polarization of Nuclei

  • 期刊论文

  • 发表日期：

    2025年2月1日

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  • V. I. Porkhun,
  • N. A. Kuznetsova,
  • A. G. Podoprigora,
  • Yu. V. Bogdanova

摘要

Abstract

Fries’ photo-rearrangement of the thioester of para-methyl benzocarbothiol in a number of solvents is studied by means of CIDNP. It is shown that the reaction proceeds with the formation of radical pairs in the singlet state. Elementary stages of the reaction are determined.