High Temperature Mass Spectrometric Study of Vaporization and Thermodynamic Properties in the Cs₂O–Al₂O₃ System

期刊论文
发表日期：

2024年12月1日

查看全文

V. A. Vorozhtcov,
V. L. Stolyarova,
A. L. Shilov,
A. V. Fedorova,
S. I. Lopatin,
S. M. Shugurov,
V. A. Stolyarov,
M. E. Pavelina

摘要

Abstract—

Using the Knudsen effusion mass spectrometric method in the temperature range 1100–1520 K, the vaporization processes and thermodynamic properties in the Cs₂O–Al₂O₃ system were studied. The data on the component activities were fitted using the Redlich–Kister polynomial to calculate the excess Gibbs energies in this system for the first time. Thermodynamic properties found in the Cs₂O–Al₂O₃ system were discussed in the frame of the generalized lattice theory of associated solutions. It was found that the Cs–O–Al bonds made the most valuable contribution to the negative deviations from the ideality in the Cs₂O–Al₂O₃ system at the temperature 1200 K.

High Temperature Mass Spectrometric Study of Vaporization and Thermodynamic Properties in the Cs2O–Al2O3 System

摘要

High Temperature Mass Spectrometric Study of Vaporization and Thermodynamic Properties in the Cs₂O–Al₂O₃ System