Producing Methanol from CO₂ on Cu–Zn-Catalyst on Commercial Supports: Effect of the Support and Conditions of the Reaction

期刊论文
发表日期：

2024年12月1日

查看全文

A. M. Batkin,
M. A. Tedeeva,
K. B. Kalmykov,
A. V. Leonov,
N. A. Davshan,
P. V. Pribytkov,
S. F. Dunaev,
I. P. Beletskaya,
A. L. Kustov

摘要

Abstract

The catalytic properties of Cu–Zn catalysts are investigated on such commercial supports as Al₂O₃, SiO₂, ZrO₂(La), TiO₂, ZnO, and activated carbon in the reaction of CO₂ hydrogenation with the production of methanol. CuZn/Al₂O₃ catalyst displays the highest conversion of CO₂. The highest selectivities toward methanol (99 and 97.5%) are observed for CuZn/ZrO₂(La) and CuZn/SiO₂ catalysts, respectively, while high values of selectivity toward CH₃OH (90–95%) are achieved in the 175–275°C range of temperatures. The highest methanol productivity is 547 g/(kg_kat h) on catalyst CuZn/ZrO₂(La). The synthesized catalysts are studied via low-temperature nitrogen adsorption, X-ray diffraction, and SEM-EDX.

Producing Methanol from CO2 on Cu–Zn-Catalyst on Commercial Supports: Effect of the Support and Conditions of the Reaction

摘要

Producing Methanol from CO₂ on Cu–Zn-Catalyst on Commercial Supports: Effect of the Support and Conditions of the Reaction