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Studying the Electrochemical Behavior of a Smooth Gold Electrode in a Solution of Bridged 1,2,4-Trioxalane in Acetonitrile

  • M. V. Polyakov,
  • M. D. Vedenyapina,
  • A. M. Skundin,
  • I. A. Yaremenko,
  • P. S. Radulov

摘要

Abstract

Cyclic voltammetry and gravimetry are used to study the behavior of a smooth gold electrode in a medium of bridged 1,2,4-trioxalane in acetonitrile. It is found that the peroxide bond in the molecule of bridged 1,2,4-trioxalane is reduced on the surface of the electrode during the cathodic process, with the subsequent formation of a diketone fragment. The formation of colloidal gold particles is detected during anodic oxidation.