Study of the Photoreaction of 2-Methyl-1-Phenyl-2-Sulfanylpropane-1-Thione Using Chemical Nuclear Polarization Effects
摘要
Abstract
The mechanisms of photoreactions of 2-methyl-1-phenyl-2-sulfanylpropane-1-thione C6H5CSC(SH)(CH3)2 (1) were studied using the chemical nuclear polarization (CNP) effect, which manifests itself in the NMR spectra [1]. While pulsed and laser photolysis makes it possible to study the kinetics of the death and accumulation of intermediate products released from the solvent cell, the use of CNP enables studies of cellular processes in detail. The multiplicity of the radical pair and the elementary acts of the reaction were established.