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Abstract <p>The synthesis and electrophysical properties of spinel ferrite ZnFe<sub>2</sub>O<sub>4</sub> obtained by solid-phase synthesis using mechanoactivation have been considered. The study encompasses a comprehensive analysis of the phase composition and crystal structure, employing X-ray powder diffraction, thermogravimetric analysis, and differential thermal analysis to elucidate the thermal effects and synthesis steps. Impedance spectroscopy has been employed to investigate the electrophysical properties, thereby confirming the considerable impact of firing temperature on electrical conductivity. The results demonstrate that the electrical conductivity of the material increases by an order of magnitude when the firing temperature is increased up to 1000°C. This suggests the potential for the use of ZnFe<sub>2</sub>O<sub>4</sub> as a cathode material for lithium-ion and metal-ion batteries. This work emphasizes the importance of optimizing synthesis conditions to achieve high performance of electrode materials.</p>

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Solid-Phase Synthesis of ZnFe2O4 and Its Electrochemical Properties

  • 期刊论文

  • 发表日期：

    2025年2月1日

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  • V. V. Efremov,
  • R. I. Korneikov,
  • S. V. Aksenova,
  • O. E. Kravchenko,
  • O. I. Akhmetov,
  • I. G. Tananaev,
  • O. O. Shichalin

摘要

Abstract

The synthesis and electrophysical properties of spinel ferrite ZnFe2O4 obtained by solid-phase synthesis using mechanoactivation have been considered. The study encompasses a comprehensive analysis of the phase composition and crystal structure, employing X-ray powder diffraction, thermogravimetric analysis, and differential thermal analysis to elucidate the thermal effects and synthesis steps. Impedance spectroscopy has been employed to investigate the electrophysical properties, thereby confirming the considerable impact of firing temperature on electrical conductivity. The results demonstrate that the electrical conductivity of the material increases by an order of magnitude when the firing temperature is increased up to 1000°C. This suggests the potential for the use of ZnFe2O4 as a cathode material for lithium-ion and metal-ion batteries. This work emphasizes the importance of optimizing synthesis conditions to achieve high performance of electrode materials.