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New Method for the Synthesis of Acetylacetone-Based closo-Borate Anion Derivatives [BnHn – 1NH=C(R)C(C(OH)CH3)C(O)CH3]–, Where n = 10, 12, R = Me, Et

  • 期刊论文

  • 发表日期：

    2024年10月29日

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  • A. V. Nelyubin,
  • N. A. Selivanov,
  • A. Yu. Bykov,
  • A. S. Kubasov,
  • I. N. Klyukin,
  • A. P. Zhdanov,
  • K. Yu. Zhizhin,
  • N. T. Kuznetsov

摘要

Abstract

The processes of nucleophilic addition of acetylacetone as a C-nucleophile to multiple bonds of nitrile derivatives of boron cluster anions have been studied in this work. The structures of the products have been established by multinuclear NMR spectroscopy, ESI-mass spectrometry, and IR spectroscopy. The structure of compound (NBu4)[2-B10H9NH=C(C2H5)C(C(OH)CH3)C(O)CH3] has been established by single crystal X-ray analysis.