Synthesis of C-Mercuro Derivatives of ortho-Carborane. Crystal Structure of Bis(2-phenyl-ortho-carboran-1-yl)mercury

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发表日期：

2024年5月1日

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S. A. Anufriev,
S. V. Timofeev,
D. I. Nasyrova,
I. B. Sivaev,
V. I. Bregadze

摘要

Abstract

Many carborane derivatives first synthesized during the rapid development of this field of chemistry in the 1960s remained completely uncharacterized by modern spectral and diffraction methods. In this work, a series of C-mercuro derivatives of ortho-carborane 1-PhHg-2-Ph-1,2-C₂B₁₀H₁₀ and (2-R-1,2-C₂B₁₀H₁₀)₂Hg (R = H, Me, Ph) were newly synthesized and characterized by NMR spectroscopy. The molecular crystal structure of bis(2-phenyl-ortho-carboran-1-yl)mercury was determined by single crystal X-ray diffraction.