Influence of Non-Adiabatic Interactions on the Lande g-Factors of the X 2Σ+ ~ A 2Π ~ B 2Σ+ Complex of the CN Radical
摘要
Abstract
The effect of the electron-rotational interaction induced by an external magnetic field on the values of Lande g-factors is systematically investigated within the quantum mechanical model of coupled radial Schredinger equations for locally and regularly perturbed electronic-vibrational-rotational (rovibronic) levels of nonadiabatically coupled X 2Σ+, A2Π and B2Σ+ states of the CN radical, whose isotopomers are of persistent astronomical interest due to their wide use in optical diagnostics of various regions of the interstellar and near-stellar medium.