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Synthesis of a Bisbenzoxazole Analogue of Hoechst 33258 as a Potential GC-Selective DNA Ligand

  • A. F. Arutyunyan,
  • M. S. Aksenova,
  • A. A. Kostyukov,
  • A. A. Stomakhin,
  • D. N. Kaluzhny,
  • A. L. Zhuze

摘要

Abstract

Using a computer modeling approach, we proposed a structure for a potential GC-specific DNA ligand, which could form a complex with DNA in the minor groove similar to that formed by Hoechst 33258 at DNA AT-enriched sites. According to this model, MBoz2A, a bisbenzoxazole ligand, was synthesized. The results of spectrophotometric methods supported the complex formation of the compound under study with DNA differing in the nucleotide composition.