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Abstract <p>Half sandwich ruthenium complexes with 5,7-dimethyl-1,3-diazaadamantane-6-one, 5,7-dimethyl-1,3-diazaadamantane, 1,5-dimethyl-3,7-diazabicyclo[3.3.1]nonan-9-one, and 1,5-dimethyl-3,7-diazabicyclo [3.3.1]nonane are prepared for the first time; their crystal structures are determined by single crystal XRD. It is established that 5,7-dimethyl-1,3-diazaadamantane can form both mononuclear and dinuclear complexes with ruthenium. In the bispidine complexes, hydrogen atoms at the nitrogen atoms are oriented at a non-typical angle.</p>

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Beyond Phosphorus: Diazaadamantane and Bispidine Analogs of RAPTA-C and RAED-C

  • 期刊论文

  • 发表日期：

    2026年3月1日

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  • A. V. Medved′ko,
  • I. A. Troshin,
  • M. E. Minyaev,
  • S. Z. Vatsadze

摘要

Abstract

Half sandwich ruthenium complexes with 5,7-dimethyl-1,3-diazaadamantane-6-one, 5,7-dimethyl-1,3-diazaadamantane, 1,5-dimethyl-3,7-diazabicyclo[3.3.1]nonan-9-one, and 1,5-dimethyl-3,7-diazabicyclo [3.3.1]nonane are prepared for the first time; their crystal structures are determined by single crystal XRD. It is established that 5,7-dimethyl-1,3-diazaadamantane can form both mononuclear and dinuclear complexes with ruthenium. In the bispidine complexes, hydrogen atoms at the nitrogen atoms are oriented at a non-typical angle.