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Abstract <p>Two new solvatomorphs of the tetranuclear Fe(III) cluster based on sulfonylcalix[4]arene are synthesized and their structures are determined by single crystal X-ray diffraction. The spin properties of the obtained complexes are studied for the first time by <sup>57</sup>Fe Mössbauer spectroscopy.</p>

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The Study of Solvatomorphism and Spin Properties of the Cluster Based on Sulfonylcalix[4]Arene

  • 期刊论文

  • 发表日期：

    2026年2月1日

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  • A. S. Ovsyannikov,
  • A. A. Iova,
  • Yu. V. Strel’nikova,
  • A. T. Gubaidullin,
  • A. V. Pyataev,
  • S. E. Solovieva,
  • I. S. Antipin

摘要

Abstract

Two new solvatomorphs of the tetranuclear Fe(III) cluster based on sulfonylcalix[4]arene are synthesized and their structures are determined by single crystal X-ray diffraction. The spin properties of the obtained complexes are studied for the first time by 57Fe Mössbauer spectroscopy.