Abstract <p>Methyl esters of 3- and 4-(5-hydroxy-5-methyl-1,3-hexadiyne-1-yl)benzoic acid (<b>1</b>, <b>2</b>) are prepared by the interaction of methyl esters of <i>meta-</i> and <i>para </i>iodobenzoic acids with 2-methylhexadiyne-3,5-ol-2. The crystal structure and structural features of <b>1</b> and <b>2</b> are determined by XRD. Thermal behavior of these compounds in argon is studied by simultaneous thermal analysis.</p>

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Synthesis, Structure, and Thermal Properties of Bifunctional Arylbuta-1,3-Diynes

  • V. S. Senchurin,
  • S. A. Nayfert,
  • A. A. Osipov,
  • D. A. Zherebtsov,
  • R. Kanthapazham,
  • D. V. Spiridonova

摘要

Abstract

Methyl esters of 3- and 4-(5-hydroxy-5-methyl-1,3-hexadiyne-1-yl)benzoic acid (1, 2) are prepared by the interaction of methyl esters of meta- and para iodobenzoic acids with 2-methylhexadiyne-3,5-ol-2. The crystal structure and structural features of 1 and 2 are determined by XRD. Thermal behavior of these compounds in argon is studied by simultaneous thermal analysis.