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Abstract <p>We present the results of the synthesis and analysis of a series of organic-soluble cluster complexes of molybdenum: (Bu<sub>4</sub>N)<sub>2</sub>[Mo<sub>6</sub>X<sub>8</sub>L<sub>6</sub>] (X&#xa0;=&#xa0;Br, I; L&#xa0;=&#xa0;–CH<sub>2</sub>=CH–COO<sup>–</sup> (acrylate, Acr<sup>–</sup>) and –CH<sub>2</sub>=C(CH<sub>3</sub>)–COO<sup>–</sup> (metacrylate, MAcr<sup>–</sup>)). The complexes are obtained by interacting (Bu<sub>4</sub>N)<sub>2</sub>[Mo<sub>6</sub>X<sub>8</sub>X<sub>6</sub>] with silver salt of the respective acid. The mentioned compounds are characterized in detail by powder and single crystal X-ray diffraction, elemental analysis, IR and NMR spectroscopy. The luminescent properties and photophysical parameters of the solid cluster complexes are studied.</p>

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A Series of Molybdenum Halide Cluster Complexes with Acrylate and Metacrylate Ligands

  • 期刊论文

  • 发表日期：

    2026年1月1日

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  • N. A. Vorotnikova,
  • C. O. Olawoyin,
  • A. S. Berezin,
  • M. A. Shestopalov,
  • Yu. A. Vorotnikov

摘要

Abstract

We present the results of the synthesis and analysis of a series of organic-soluble cluster complexes of molybdenum: (Bu4N)2[Mo6X8L6] (X = Br, I; L = –CH2=CH–COO– (acrylate, Acr–) and –CH2=C(CH3)–COO– (metacrylate, MAcr–)). The complexes are obtained by interacting (Bu4N)2[Mo6X8X6] with silver salt of the respective acid. The mentioned compounds are characterized in detail by powder and single crystal X-ray diffraction, elemental analysis, IR and NMR spectroscopy. The luminescent properties and photophysical parameters of the solid cluster complexes are studied.