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Abstract <p>Polymeric silver terephthalate [Ag<sub>2</sub>(ter)] (<b>1</b>) (ter<sup>2–</sup>&#xa0;=&#xa0;O<sub>2</sub>C-C<sub>6</sub>H<sub>4</sub>-CO<sub>2</sub>) and malonate [Ag<sub>2</sub>(malo)] (<b>2</b>) (malo<sup>2–</sup>&#xa0;=&#xa0;O<sub>2</sub>C-CH<sub>2</sub>-CO<sub>2</sub>) are obtained and characterized by the elemental analysis and IR spectroscopy. When heated, these complexes dissolve in pyridine (py) or its derivatives. The crystals of MOFs [Ag(py)<sub>4</sub>](Hter) (<b>3a</b>), [Ag<sub>2</sub>(3-Me-py)<sub>4</sub>(ter)] (<b>4a</b>), [Ag<sub>2</sub>(3-Me-py)<sub>4</sub>(malo)] (<b>5a</b>) are obtained from solutions. Single crystals are analyzed by X-ray diffraction, however, they rapidly decompose with a loss of py molecules if they are isolated from the mother liquor or slightly heated. Stable products of <b>3a</b>, <b>4a</b>, <b>5a</b> desolvation and decoordination are [Ag<sub>2</sub>(py)<sub>2.8</sub>](Hter)<sub>2</sub> (<b>3</b>), [Ag<sub>2</sub>(3-Me-py)<sub>1.3</sub>(ter)] (<b>4</b>), [Ag<sub>2</sub>(3-Me-py)<sub>2.9</sub>(malo)] (<b>5</b>).</p>

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MOFs Based on Silver Terephthalate and Malonate

  • 期刊论文

  • 发表日期：

    2025年11月1日

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  • D. K. Zhuravlev,
  • I. V. Korolkov,
  • M. N. Sokolov,
  • P. A. Abramov

摘要

Abstract

Polymeric silver terephthalate [Ag2(ter)] (1) (ter2– = O2C-C6H4-CO2) and malonate [Ag2(malo)] (2) (malo2– = O2C-CH2-CO2) are obtained and characterized by the elemental analysis and IR spectroscopy. When heated, these complexes dissolve in pyridine (py) or its derivatives. The crystals of MOFs [Ag(py)4](Hter) (3a), [Ag2(3-Me-py)4(ter)] (4a), [Ag2(3-Me-py)4(malo)] (5a) are obtained from solutions. Single crystals are analyzed by X-ray diffraction, however, they rapidly decompose with a loss of py molecules if they are isolated from the mother liquor or slightly heated. Stable products of 3a, 4a, 5a desolvation and decoordination are [Ag2(py)2.8](Hter)2 (3), [Ag2(3-Me-py)1.3(ter)] (4), [Ag2(3-Me-py)2.9(malo)] (5).