Binuclear Bi(III) Bromide Complexes with 1,1′-(alkane-1,X-diyl)Bis(3,5-dimethyl)Pyridine Dications
摘要
Abstract
Complexes {(3,5-MePy)2(CH2)n}3[Bi2Br9]2 (n = 2 (1), 5 (2)) are obtained by the reaction of bismuth oxide with salts of various doubly charged cations based on 3,5-dimethylpyridine in concentrated HBr, and they are structurally characterized by X-ray diffraction. The features of intermolecular contacts in the crystal structure are considered.