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Abstract <p>The reaction of bisnitronylnitroxide with a diacetylene bridging group and diazomethane leads to the modification of the initial substrate while preserving its paramagnetic centers. As a result, new nitronylnitroxide biradicals containing a bispyrazolyl fragment were prepared. Molecular and crystal structures of the biradicals are determined by single crystal XRD.</p>

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Synthesis and Structure of Bispyrazolyl Nitronylnitroxide Biradicals

  • 期刊论文

  • 发表日期：

    2025年8月29日

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  • S. E. Tolstikov,
  • G. V. Romanenko,
  • E. V. Tretyakov,
  • A. S. Bogomyakov

摘要

Abstract

The reaction of bisnitronylnitroxide with a diacetylene bridging group and diazomethane leads to the modification of the initial substrate while preserving its paramagnetic centers. As a result, new nitronylnitroxide biradicals containing a bispyrazolyl fragment were prepared. Molecular and crystal structures of the biradicals are determined by single crystal XRD.