Abstract <p>Single crystals of chiral coordination polymer [Zn(<i>R</i>-Hhhm)<sub>2</sub>] (<b>1</b>) are obtained in the interaction of zinc acetate and <i>R</i>-hexahydromandelic acid (<i>R</i>-H<sub>2</sub>hhm) in a water-methanol solution. The compound has a chain structure, which is determined by single crystal X-ray diffraction with synchrotron radiation. Coordination polymer [Zn(<i>R</i>-Hhhm)<sub>2</sub>] is the first example of the structurally characterized coordination compound containing hexahydromandelic acid anions.</p>

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Structure of the Coordination Polymer Based on Zinc and R-Hexahydromandelic Acid

  • M. S. Zavakhina,
  • D. G. Samsonenko,
  • P. V. Dorovatovskii,
  • V. A. Lazarenko

摘要

Abstract

Single crystals of chiral coordination polymer [Zn(R-Hhhm)2] (1) are obtained in the interaction of zinc acetate and R-hexahydromandelic acid (R-H2hhm) in a water-methanol solution. The compound has a chain structure, which is determined by single crystal X-ray diffraction with synchrotron radiation. Coordination polymer [Zn(R-Hhhm)2] is the first example of the structurally characterized coordination compound containing hexahydromandelic acid anions.